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Keyword:upconversion luminescence  yttrium sodium tungstate: rare earth ions 
Classification:TB321
Year,volume(Issue):page number:2018,46(1):0-0
Summary:
Nd3+/Yb3+/Tm3+ co-doped NaY(WO4)2 nanocrystals were prepared by a hydrothermal method. The crystal structure,morphology and up-conversion luminescent properties of samples were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy and luminescence spectroscopy, respectively. The results indicate that all the synthesized samples are a pure tetragonal phase of NaY(WO4)2, and the particle sizes are 50–55 nm. The up-conversion nanoparticles have a small size,well-dispersive property and water solubility by adding polyethylene glycol (i.e., PEG-2000) as a surfactant. For NaY(WO4)2:Nd3+/Yb3+/Tm3+, a blue emission peak at 469 nm and a green emission peak at 539 nm appear under  808-nm excitation. The blue emitting light results from the energy level transition of 1G4?3H6 of Tm3+, green emitting light is from the transition of 1D2?3H5 of Tm3+. In addition, the energy transfer process and the up-conversion luminescence mechanism of Nd3+? Yb3+?Tm3+ in co-doped system were also investigated.
 
Foundation item:
国家重点研发计划项目(2017YFB0310300);国家自然科学基金(51274052);辽宁省自然科学基金 (201602134);辽宁省教育厅(JDL2016002) 资助项目。
About The Author:
史忠祥(1989—),男,博士研究生。
References:
[1] VENNERBERG Danny, LIN Zhiqun. Upconversion nanocrystals: synthesis, properties, assembly and applications[J]. Sci Adv Mater, 2011, 3(1): 26–40.
[2] LI Jiajia, LI Ting, SUO Hao, et al. Up-conversion emission color tuning in NaLa(MoO4)2:Nd3+/Yb3+/Ho3+ excited at 808 nm[J]. Ceram Int, 2017, 43: 6333–6339. 
[3] JIANG Guicheng, ZHOU Shaoshuai, WEI Xiantao, et al. 794 nm excited core-shell upconversion nanoparticles for optical temperature sensing[J]. Rsc Adv, 2016, 6(14): 11795–11801.
[4] WANG Danmian, FAN Haihua, CHEN Zhimin, et al. Upconversion luminescence of Eu3+ ion in aluminoborate/NaYF4 vitreous composite matrix induced by 800 nm laser[J]. J Alloy Compd, 2016, 657: 115–121.
[5] XUE Xiaojie, QING Weiping, ZHANG Daisheng, et al. Synthesis and upconversion luminescence of NaYF4: Yb3+,Tm3+/TiO2 nanocrystal colloidal solution[J]. J Nanosci Nanotechnol, 2010, 10(3): 2028–2031.
[6] ZHENG Wei, HUANG Ping, TU Datao, et al. Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection[J]. Chem Soc Rev, 2015, 44(6): 1379–1415.
[7] WANG Dan, XUE Bin, KONG Xianggui, et al. 808 nm driven Nd3+-sensitized upconversion nanostructures for photodynamic therapy and simultaneous fluorescence imaging[J]. Nanoscale, 2015, 7(1): 190–197.
[8] BI Wenbo, MENG Qingyu, SUN Wenjun, et al. Optical temperature sensing properties of Er3+,Yb3+ co-doped NaGd(MoO4)2 phosphor[J]. Ceram Int, 2017, 43(1): 1460–1465.
[9] ZHOU Yongqiang, WANG He, XU Bin, et al. Concentration- dependent up-converted luminescence of Ho3+-Yb3+ co-doped yttrium-stabilized zirconia phosphors[J]. J Lumin, 2015, 161: 288–292.
[10] WU Dan, HAO Zhendong, XIAO Wenge, et al. The dominant role of excitation diffusion in energy transfer upconversion of Lu2O3: Tm3+,Yb3+[J]. J Alloy Compd, 2017, 704: 206–211.
[11] TANG Jianfeng, GOU Jie, LI Guannan, et al. Tunable upconversion luminescence from the phosphors of Yb3+, Tm3+ and Ho3+ tri-doped Re2TeO6 (Re = La, Gd, and Lu)[J]. J Alloy Compd, 2016, 672: 1–6.
[12] WANG Yefu, LIU Gaoyuan, SUN Lingdong, et al. Nd3+-sensitized upconversion nanophosphors: Efficient in vivo bioimaging probes with minimized heating effect[J]. ACS Nano, 2013, 7(8): 7200–7206.
[13] DONG Xiaobin, YOU Fangtian, PENG Hongshang, et al. Ultraviolet to near-infrared energy transfer in NaYF4:Nd3+,Yb3+ crystals[J]. J Rare Earth, 2016, 34(9): 863–867.
[14] 叶帅, 宋军, 陈林春, 等. Nd3+掺杂的NaYF4:Yb,Er/Tm上转换纳米颗粒的光谱分析[J]. 光学学报, 2015, 35(8): 0816005(1–5).
YE Shuai, SONG Jun, CHEN Linchun, et al. Acta Opt Sin (in Chinese), 2015, 35(8): 0816005(1–5).
[15] XU Sai, XIANG Suyuan, ZHANG Yanqiu, et al. 808 nm laser induced photothermal effect on Sm3+/Nd3+ doped NaY(WO4)2 microstructures[J]. Sens Actuators B Chem, 2017, 240: 386–391.
[16] LI Minhong, WANG Lili, RAN Weiguang, et al. Tunable emission of single-phased NaY(WO4)2:Sm3+ phosphor based on energy transfer[J]. Ceram Int, 2017, 43(9): 6751–6757.
[17] XIANG Suyuan, ZHENG Hui, ZHANG YAnqiu, et al. Effect of Tm3+ Concentration and temperature on blue and NIR upconversion luminescence in Tm3+/Yb3+ co-doped NaY(WO4)2 microstructures[J]. J Nanosci Nanotechnol, 2016, 16(1): 636–642.
[18] LIU Ting, MENG Qingyu, SUN Wenjun. Luminescent properties of Eu3+ doped NaY(WO4)2 nanophosphors prepared by molten salt method[J]. J Rare Earth, 2015, 33(9): 915–921.
[19] JIA Yutao, SONG Yinglin, BAI Yunfeng, et al. Upconverted photoluminescence in Ho3+ and Yb3+ codoped Gd2O3 nanocrystals with and without Li+ ions[J]. Luminescence, 2011, 26(4): 259–263.
[20] CUNEYT TAS A. Formation of calcium phosphate whiskers in hydrogen peroxide (H2O2) solutions at 90 ℃[J]. J Am Chem Soc, 2007, 90(8): 2358–2362. 
[21] 赵文新. 软化学法制备稀土掺杂的钨酸盐发光材料[D]. 长春: 长春理工大学, 2011.
ZHAO Wenxin. Preparation of rare earth doped tungstate luminescent materials by soft chemical method (in Chinese, dissertation). Changchun: Changchun University of Science and Technology, 2011. 
[22] SUN Daxi. Hydrothermal synthesis of NaY(WO4)2:Tb3+ powders with assistance of surfactant and luminescence properties[J]. J Mater Sci: Mater Electron, 2015, 26: 6892–6896.
[23] HUANG Yanlin, FENG Qiang, YANG Yu. A study of luminescence properties in the boron-doped lead tungstate[J]. Phys Lett A, 2005, 336(6): 490–497.
[24] 张树鹏. 聚乙二醇/功能化石墨烯层状纳米复合材料热稳定性的提高[J]. 化学学报, 2012, 70(12): 1394–1400.
ZHANG Shupeng. Acta Chim Sin (in Chinese), 2012, 70(12): 1394–1400.
[25] 肖燕. 核壳结构纳米晶制备和修饰及其上转换荧光性质[D]. 哈尔滨: 哈尔滨工业大学, 2012.
XIAO Yan. Preparation and upconversion emissions properties and PEG modification of nanocrystalline with nanocrystalline with core-shell structure (in Chinese, dissertation). Harbin: Harbin Institute of Technology, 2012. 
[26] 宣琎楠, 李娜, 王茗, 等. PEG修饰NaGdF4:Yb3+/Er3+纳米粒子合成及上转换发光性质[J]. 人工晶体学报, 2015, 44(8): 2245–2249.
XUAN Jinnan, LI Na, WANG Ming, et al. J Synth Cryst (in Chinese), 2015, 44(8): 2245–2249.
[27] 杨健芝, 邱建备, 杨正文, 等. Ba5SiO4Cl6:Yb3+,Er3+,Li+ 荧光粉的制备及上转换发光性质研究[J]. 物理学报, 2015, 64(13): 138101(1–6).
YANG Jianzhi, QIU Jianbei, YANG Zhengwen, et al. Acta Phys Sin (in Chinese), 2015, 64(13): 138101(1–6).
[28] 刘磊, 杨魁胜, 贺超, 等. Yb3+/Tm3+共掺杂的钨酸镉纳米晶发光性能的研究[J]. 无机化学学报, 2013, 29(6): 1123–1128.
LIU Lei, YANG Kuisheng, HE Chao, et al. Chin J Inorg Chem (in Chinese), 2013, 29(6): 1123–1128.
[29] 王萍, 杨定明, 何晓林, 等. 近紫外激发的Na2ZnSiO4: Sm3+橙红色荧光粉的合成及发光性能[J]. 人工晶体学报, 2015, 44(6): 1534–1538.
WANG Ping, YANG Dingming, HE Xiaolin, et al. J Synth Cryst (in Chinese), 2015, 44(6): 1534–1538.
 
 
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