首页期刊信息编委及顾问期刊发行联系方式使用帮助常见问题ENGLISH
位置:首页 >> 正文
固体氧化物燃料电池双钙钛矿型电极材料的研究进展
作者:谢志翔 赵海雷 周雄 沈永娜  
单位:北京科技大学材料学院无机非金属材料系 新能源材料与技术北京市重点实验室  
关键词:固体氧化物燃料电池  电极材料  双钙钛矿结构  综述 
分类号:TM911.4
出版年,卷(期):页码:2010,38(6):1140-1144
DOI:
摘要:

电极材料对固体氧化物燃料电池(solid oxide fuel cell,SOFC)工作特性具有重要影响。双钙钛矿型A2BB′O6氧化物材料由于具有较强的氧离子传输能力、较低的膨胀系数、良好的催化活性、较强的抗硫中毒和抗碳沉积能力,成为非常有发展潜力的SOFC电极材料,其双B位元素特征使材料具有更强的结构和性能可调节性。本文综述双钙钛矿型氧化物材料作为SOFC电极材料的最新研究进展,重点总结双钙钛矿型电极材料的结构稳定性、电子和离子电导率以及电催化活性,指出目前双钙钛矿电极材料存在的主要问题,并提出未来的主要研究方向。

women want men infidelity signs how do i know if my wife cheated
redirect husband cheated unfaithful husband
open cheat women go
why do wife cheat on husband women that cheat with married men how to cheat wife
my husband cheated on me men who have affairs women who cheat on husband
printable coupons for cialis outbackuav.com coupon for free cialis

Electrode materials have strong impact on operation performance of solid oxide fuel cells (SOFCs). Due to the high trans-portation ability for oxygen ions,the low thermal expansion coefficient,good catalytic activity and high tolerance to sulfur poisoning and strong resistance against carbon deposition,the double-perovskite A2BB'O6 oxide becomes a promising electrode material for the SOFCs. The double B-site characteristic in double-perovskite oxides has strong controllability on lattice structure and properties. In this paper,the recent progress on double-perovskite based electrode materials for SOFCs is reviewed. The emphasis focuses on their structure stability,electronic and ionic conductivity as well as catalytic activity. The main concerns about current double-perovskite based electrode materials are summarized and the main future research directions are proposed.

married cheaters how many women cheat click
how do i know if my wife has cheated dating for married men read
基金项目:
国家自然科学基金(20973021);; 国家“863”计划(2006AA11–A189)资助项目
作者简介:
online want my wife to cheat married woman looking to cheat
open cheat women go
cialis discount coupons coupons for cialis 2016 cialis 2015 coupon
参考文献:

[1]JOON K.Fuel cells—a21st century power system[J].J Power Sources,1998,71:12–18. [2]MURRAY P E,TSAI T,BAMETT S A.Adirect-methane fuel cell with a ceria-based anode[J].Nature,1999,400:649–651. [3]MUKUNDAN R,BROSHA E L,GARZON F H.Sulfur tolerant anodes for SOFCs[J].Electrochem Solid-State Lett,2004,7:A5–A7. [4]DOSHI R,RICHARDS V L,CARTER J D,et al.Development of solid-oxide fuel cells that operate at500℃[J].J Electrochem Soc,1999,146:1273–1278. [5]SIMNER S P,BONNETT J F N L,et al.Development of lanthanum ferrite SOFC cathodes[J].J Power Sources,2003,113:1–10. [6]TAO S W,IRVINE J T S.Structure and properties of nonstoichiometric mixed perovskites A3B′1+xB″2·xO9·δ[J].Solid State Ionics,2002,154/155:659–667. [7]李海军.双层钙钦矿型甲烷燃烧催化剂的制备及表征[D].内蒙古:内蒙古大学,2007.LI Haijun.The study on catalytic combustion properties of methane over double perovskite catalysts(in Chinese,dissertation).Neimengu:Neimengu University,2007. [8]TAO S W,CANALES J V,IRVINE J T S.Structural and electrical properties of the perovskite oxide Sr2FeNbO6,chemistry of material[J].2004,16:2309–2316. [9]XIA T,LIU X D,LI Q,et al.Synthesis,structural and electrical charac-terizations of Sr2Fe1·xMxNbO6(M=Zn and Cu)with double perovskite structure[J].J Alloys Compd,2006,422:264–272. [10]THANGADURAI V,SHUKLA A K,GOPALAKRISHNAN J.Oxide-ion conduction in anion-deficient double perovskites Ba2BB′O5.5(B=Li,Na;B′=Mo,W,Te)[J].Solid State Ionics,1997,104:277–283. [11]HUANG Y H,DASS R L,XING Z L,et al.Double perovskites as anode materials for solid-oxide fuel cells[J].Science,2006,312:254–257. [12]HUANG Y H,DASS R L,DENYSZYN J C,et al.Synthesis and characterization of Sr2MgMoO6–δan anode material for the solid oxide fuel cell[J].J Electrochem Soc,2006,153:A1266–A1272. [13]BERMUY-LOPEZ L C,M ALLIX M,BRIDGES C A,et al.Sr2MgMoO6–δ:structure,phase stability,and cation site order control of reduction[J].Chem Mater,2007,19:1035–1043. [14]MATSUDA Y,KARPPINEN M,YAMAZAKI Y,et al.Oxygen-vacancy concentrationin Sr2MgMoO6–δdouble-perovskiteoxides[J].J Solid State Chem,2009,182:1713–1716. [15]JI Y,HUANG Y H,YING J R,et al.Electrochemical performance of La-doped Sr2MgMoO6–δin natural gas[J].Electrochem Commun,2007,9:1881–1885. [16]MARRERO-LOPEZ D,PENA M J,RUIZ M J C,et al.High temperature phase transition in SOFC anodes based on Sr2MgMoO6–δ[J].J Solid State Chem,2009,182:1027–1034. [17]MARRERO-LOPEZ D,PENA M J,RUIZ M J C,et al.Synthesis phase stability and electrical conductivity of Sr2MgMoO6–δanode[J].Mater Res Bull,2008,43:2441–2450. [18]HUANG Y H,LIANG G,CROGT M,et al.Double-perovskite anode materials Sr2MMoO6(M=Co,Ni)for solid oxide fuel cells[J].ChemMater,2009,21:2319–2326. [19]WEI T,JI Y,MENG X W,et al.Sr2NiMoO6–δas anode material for LaGaO3-based solid oxide fuel cell[J].Electrochem Commun,2007,10:1369–1372. [20]XIA T,LIN N,ZHAO H,et al.Co-doped Sr2FeNbO6as cathode materials for intermediate-temperature solid oxide fuel cells[J].J Power Sources,2009,192:291–296. [21]FAUTH F,SUARD E,CAIGNAERT V,et al.Interplay of structural,magnetic and transport properties in the layered Co-based perovskite LnBaCo2O5(Ln=Tb,Dy,Ho)[J].Eur Phys J B,2001,21:163–174. [22]RESPAUD M,FRONTERA C,GARCIA M J L,et al.Magnetic and magnetotransport properties of GdBaCo2O5+δ:a high magnetic-field study[J].Phys Rev B,2001,64:214401. [23]ROY S,DUBENKO I S,KHAN M,et al.Magnetic properties of perovskite-derived air-synthesized RBaCo2O5+δ(R=La Ho)compounds[J].Phys Rev B,2005,71:024419. [24]KIM G,WANG S,JACOBSON A J,et al.Oxygen exchange kinetics of epitaxial PrBaCo2O5+δthin films[J].Appl Phys Lett,2006,88:024103. [25]KIM G,WANG S,JACOBSON A J,et al.Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cations[J].J Mater Chem,2007,17:2500–2505. [26]TASKIN A A,LAVROV A N,ANDO Y.Achieving fast oxygen diffu-sion in perovskites by cation ordering[J].Appl Phys Lett,2005,86:091910. [27]MAIGNAN A,MARTIN C,PELLOQUIN D,et al.Structural and magnetic studies of ordered oxygen-deficient perovskites LnBaCo2O5+δ,closely related to the“112”structure[J].J Solid State Chem,1999,142:247–260. [28]ZHANG K,GE L,RAN R,et al.Synthesis,characterization and evaluation of cation-ordered LnBaCo2O5+δas materials of oxygen permeation membranes and cathodes of SOFCs[J].Acta Materialia,2008,56:4876–4889. [29]TARANCON A,MARRERO D L,PEN J M,et al.Effect of phase transition on high-temperature electrical properties of GdBaCo2O5+x layered perovskite[J].Solid State Ionics,2008,179:611–618. [30]MORI M,SAMMES N M.Sintering and thermal expansion charac-terization of Al-doped and Co-doped lanthanum strontium chromites synthesized by the Pechini method[J].Solid State Ionics,2002,146:301–312. [31]LI N,LU Z,WEI B,et al.Characterization of GdBaCo2O5+δcathode for IT-SOFCs[J].J Alloys Compd,2008,454:274–279. [32]LEE K T,MANTHIRAM A.Effect of cation doping on the physical properties and electrochemical performance of Nd0.6Sr0.4Co0.8M0.2O3·δ(M=Ti,Cr,Mn,Fe,Co,and Cu)cathodes[J].Solid State Ionics,2007,178:995–1000. [33]JO S H,MURALIDHARAN P,KIM D K.Enhancement of electroche-mical performance and thermal compatibility of GdBaCo2/3Fe2/3·Cu2/3O5+δcathode on Ce1.9Gd0.1O1.95electrolyte for IT-SOFCs[J].Elec-trochem Commun,2009,11:2085–2088.

online want my wife to cheat married woman looking to cheat
redirect husband cheated unfaithful husband
how to catch a cheater redirect go
my wife cheated on me now what website husband cheat
服务与反馈:
文章下载】【加入收藏
中国硅酸盐学会《硅酸盐学报》编辑室
京ICP备10016537号-2
京公网安备 11010802024188号
地址:北京市海淀区三里河路11号    邮政编码:100831
电话:010-57811253  57811254    
E-mail:jccs@ceramsoc.com