硅酸盐学报

硫系红外玻璃材料耐辐射性能研究进展

单位：1. 南京邮电大学光电工程学院南京 210046 2. 中国科学院西安光学精密机械研究所瞬态光学与

关键词：耐辐射硫系玻璃辐照效应研究进展

分类号：TQ171.1

出版年,卷(期):页码：2012,40(8):1229-1229

DOI：

摘要：

摘要：硫系玻璃在航空航天、核子反应监测与探测等领域有着广阔的发展前景和重要的应用价值，是目前光电子技术领域中最受关注的材料之一。本文对近年来国内外关于硫系玻璃耐辐照性能研究的相关情况进行了综合评述，重点阐述了硫系玻璃在γ射线辐照环境中的损伤机理，同时对影响耐辐照性能的因素进行分析，提出了增强硫系玻璃耐辐照性能的可行途径，最后展望了未来该领域的研究方向和发展前景。

Abstract: Chalcogenide glass has great prospects and important applications in the aerospace, nuclear reaction monitoring and detection. It has become one of the most concerned materials in the field of photonics technology. This review represents recent developments on the studies of chalcogenide glass irradiation resistance properties, and emphases on the damage mechanism at gamma radiation. The factors influencing the irradiation resistance properties of chalcogenide glass were analyzed and the feasible ways for enhancing the irradiation resistance properties were discussed. In addition, some further studies on this aspect were given.

基金项目：

国家自然科学基金(61177084)资助项目。

作者简介：

第一作者：孟伟(1987—)，男，硕士研究生。通信作者：郭海涛(1980—)，男，博士，副研究员。

参考文献：

参考文献：
[1] ADREICHIN R, NIKIFOROVA M, SKORDEVA E, et al. Structure and physical properties of the glassy As2S3Gex system [J]. J Non-Cryst Solids, 1976, 20(1): 101–122.
[2] EICHHOM U, FRISCHAT G H. Self-diffusion in the chalcogenide glass system Se Ge As [J]. J Non-Cryst Solids, 1978, 30(2): 211–220.
[3] VIENS J F, MENEGHINI C, VILLENEUVE A, et al. Fabrication and characterization of integrated optical waveguides in sulfide chalcogenide glasses [J]. J Lightwave Technol, 1999, 17(7): 1184–1191.
[4] HOUIZOT P, BOUSSARD-PLEDEL C, FABER A J, et al. Infrared single mode chalcogenide glass fiber for space [J]. Opt Express, 2007, 15(19): 12529–12538.
[5] COMPTON A H. A quantum theory of the scattering of X-rays by light elements [J]. Phys Rev Letter, 1923, 21(5): 483–501.
[6] SHPOTYUK O I, KOVALSKIY A P, SKORDEVA E, et al. Effect of gamma-irradiation on the optical properties of GexAs40–xS60 glasses [J]. Physica B, 1999, 271(1–4): 242–247.
[7] 曹志峰. 特种光学玻璃[M]. 北京: 兵器工业出版社, 1993: 54–55.
CAO Zhifeng. Special Optical Glass (in Chinese). Beijing: The Publish of Weapon Industry. 1993: 54–55.
[8] OVSHINSKY S R, EANS E J, NELSON D L, et al. Radiation hardness of ovonic devices [J]. Ieeet Nucl Sci, 1986, 15(6): 311–321.
[9] EDMOND J T, MALE J C, CHESTER P F. On the suitability of liquid semiconductors for resistance thermometry in nuclear reactors [J]. J Scient Instr: J Phys E, 1968, 1(4): 373–378.
[10] STARODUBCEV S V, DOMORYAD I A, KHIZNICHENKO L P. Changes of mechanical characteristics of amorphous selenium under gamma-ray influence [J]. USSR Acad Sci, 1961, 139(6): 562–594.
[11] SARSEMBINOV S H, ABDULGAFAROV E E, TUMANOV M, et al. Radiation-induced defects influence on the electrical, photoelectrical and optical properties of chalcogenide glasses [J]. J Non-Cryst Solids, 1980, 35–36(2): 877–882.
[12] SHPOTYUK O I, MATKOVSKYA A O, KOVALSKYA A P, et al. Radiation-induced changes of amorphous As2S3 physical properties [J]. Radiat Eff Defect S, 1995, 133(1): 1–4.
[13] BALITSKA V O, SHPOTYUK O I. Radiation-induced structural transformations in vitreous chalcogenide semiconductors [J]. J Non-Cryst Solids, 1998, 227–230(2): 723–727.
[14] SHPOTYUK O I, KOVALSKII A P, VAKIV M M, et al. Reversible radiation effects in vitreous As2S3. I. changes of physical properties [J]. Phys Status Solidi, 1994, 144(2): 277–283.
[15] SHPOTYUK O I. Reversible radiation effects in vitreous As2S3. II. mechanism of structural transformations [J]. Phys Status Solidi A, 1994, 145(1): 69–75.
[16] GOLOVCHAKY R YA, SHPOTYUK O I. Radiation-induced bond switching in mixed Ge-As sulphide glasses [J]. Philos Mag, 2005, 85(25): 2847–2860.
[17] MAGED A F, WAHAB L A, EL K I A, et al. Effect of Te addition on some physical properties of the Se3S2 system and a study of the response to γ-irradiation [J]. J Mater Sci, 1998, 33(13): 3331–3335.
[18] DEBOLT M A, EASTEAL A J, MACEDO P B, et al. Analysis of structural relaxation in glass using rate heating data [J]. J Am Ceram Soc, 1976, 59(1–2): 16–21.
[19] GOLOVCHAK R YA, KOZDRAS A, GORECKI C Z, et al. Gamma irradiation induced physical ageing in As-Se glasses [J]. J Non-Cryst Solids, 2006, 352(42–49): 4960–4963.
[20] GOLOVCHAK R. High-energy γ-irradiation effect on physical ageing in Ge–Se glasses [J]. Nucl Instrum Meth B, 2009, 267(17): 2958– 2961.
[21] GOLOVCHAK R YA, KOZDRAS A, SHPOTYUK O I. Physical ageing in vitreous As13.5Ge4.5Se82 modi?ed by high-energy gamma- irradiation [J]. Physica B, 2006, 371(2): 323–326.
[22] IMRAN M M A, AL-HAMARNEH I F, AWADALLAH M I, et al. Physical ageing in Se94Sn6 glass induced by gamma irradiation [J]. Physica B, 2008, 403(17): 2639–2642.
[23] BALITSKA V, KOVALSKIY A, SHPOTYUK O, et al. On the instability effects in radiation-sensitive chalcogenide glasses [J]. Radiat Meas, 2007, 42(4–5): 941–943.
[24] BALITSKA V, SHPOTYUK O I, ALTENBURG H. Bimolecular relaxation kinetics observed in radiation-optical properties of Ge– As(Sb)–S glasses [J]. J Non-Cryst Solids, 2006, 352(42–49): 517–520.
[25] XIA Fang, BACCARO S, ZHAO Donghui, et al. Gamma ray irradiation induced optical band gap variations in chalcogenide glasses [J]. Nucl Instrum Meth B, 2005, 234(4): 525–532.
[26] KOLOMIETS B T, MAMONTOVA T N, DOMORYAD I A, et al. Photoluminescence in γ-irradiated vitreous and monocrystalline As2S3 and As2Se3 [J]. Phys Stat Sol (a), 1971, 7(1): 29–32.
[27] GOLOVCHAK R, SHPOTYUK O I, KOZDRAS A, et al. Radiation effects in physical aging of binary As-S and As-Se glasses [J]. Mater Sci Eng, 2010, 103(1): 213–218.
[28] SKORDEVA E, ARSOVA D, PAMUKCHIEVA V, et al. Gamma- induced changes in Ge–As–S glasses [J]. J Optoelectron Adv M, 2000, 2(3): 259–266.

服务与反馈：

【文章下载】【加入收藏】