硅酸盐学报

基于背散射电子图像的矿渣-水泥复合体系反应程度的定量分析

作者：张倩倩魏亚

单位：清华大学土木工程系土木工程安全与耐久教育部重点实验室北京 100084

关键词：清华大学土木工程系土木工程安全与耐久教育部重点实验室北京 100084)

分类号：TU528

出版年,卷(期):页码：2015,43(5):563-569

DOI：10.14062/j.issn.0454-5648.2015.05.03

摘要：

采用基于背散射电子图像(BSE)的物相灰度定量分析法研究了矿渣-水泥复合体系中水泥、矿渣各自反应程度及总体

反应程度。结果表明：表面足够平滑的样品，其BSE 图像可以清晰地展示出复合体系中水化产物及未反应颗粒的微观形貌及

其差异，并可通过灰度统计定量分析得到水泥、矿渣各自的反应程度；对于低水胶比(0.3)的矿渣-水泥复合体系，矿渣掺量为

50%和70%时，矿渣反应程度接近。由BSE 图像分析法计算得到的矿渣-水泥复合体系总体反应程度比基于化学结合水的热

重分析法所测数据偏低，但两种方法揭示出的规律一致：对于低水胶比的矿渣-水泥复合体系，高矿渣掺量会减小矿渣-水泥

复合体系的总体反应程度。

A quantitative analysis on the gray scale of the different phases of the back-scattered-electron (BSE) images was carried

out for the purpose of investigating the reaction degree in slag-cement composite system. The results show that the BSE images of the

samples with sufficiently smooth surfaces can clearly display the different microstructure of hydration products and the unreacted

grain in the intricate composite system. In addition, the statistics of the gray scale can also give the quantitative information regarding

the degree of hydration of the slag and the cement. For a low water-binder ratio (0.3) slag-cement composite system, there is little

difference between the degrees of hydration reaction of slag at the slag contents of 50% and 70%. The calculated degree of hydration

of the slag-cement composite system based on the BSE image analysis is lower than that from the thermal gravity analysis based on

the chemically-bond water in the system. A great content of slag content cannot enhance the overall hydration reaction of the

slag-cement composite system for a low water-to-binder ratio composite system.

基金项目：

国家自然科学基金项目(51108246)。

作者简介：

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