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自愈合C/C复合材料的研究现状与展望
作者:李贺军 陈苗苗 姚西媛   贾瑜军   
单位:西北工业大学炭/炭复合材料工程技术研究中心 西安 710072 
关键词:碳/碳复合材料 自愈合 氧化 
分类号:TQ332
出版年,卷(期):页码:2018,46(1):142-149
DOI:
摘要:

C/C复合材料在450 ℃以上的氧化严重制约着其作为超高温结构材料的应用,宽温域自愈合抗氧化是未来C/C复合材料的发展方向。综述了高、中、低温3种自愈合类型,概括了自愈合抗氧化技术在成分和结构设计等方面的研究现状,并提出了目前C/C复合材料自愈合抗氧化研究中存在的问题和下一步的研究方向。

 The oxidation of C/C composites at high temperature over 450 ℃ severly restricts its application as high temperature structural materials. Self-healing of C/C composites in wide temperature range for against oxidation is the future development direction. The research status of three kinds of self healing, including low-temperature self healing, mediate-temperature self healing and high-temperature self healing, two aspects of component design and structural design of self-healing technique were summarized. The present problems and the potential development direction on the investigation of self healing of C/C composites for against oxidation at high temperature are also proposed.

基金项目:
国家自然科学基金(51521061,51502245);凝固技术国家重点实验室研究基金(142–TZ–2016)资助项目。
作者简介:
李贺军(1957—),男,博士,教授。
参考文献:
[1] LI H J. Carbon/Carbon Composites[J]. New Carbon Mater, 2001, 16(2): 79–80.
[2] 付前刚, 李贺军, 沈学涛, 等. 国内C/C复合材料基体改性研究进展[J]. 中国材料进展, 2011, 30(11): 6–12.
FU Qiangang, LI Hejun, SHEN Xuetao, et al. Mater China(in Chinese), 2011, 30(11): 6–12.
[3] 张伟刚. 碳/碳复合材料的宽温域自愈合抗氧化[J]. 中国材料进展, 2011, 30(11): 25–31.
ZHANG Weigang. Mater China(in Chinese), 2011, 30(11): 25–31.
[4] OUYANG H H, LI C Y, HUANG J F, et al. Self-healing ZrB2–SiO2 oxidation resistance coating for SiC coated carbon/carbon composites[J]. Corros Sci, 2016, 110: 265–272.
[5] 郑晓慧, 堵永国, 肖加余, 等. 自愈合碳纤维增强陶瓷基复合材料研究进展[J]. 材料工程, 2008(5): 75–80.
ZHENG Xiaohui, DU Yongguo, XIAO Jiayu, et al. J Mater Eng(in Chinese), 2008(5): 75–80.
[6] 张立同, 成来飞, 徐永东, 等. 自愈合碳化硅陶瓷基复合材料研究及应用进展[J]. 航空材料学报, 2006, 26(3): 226–232.
ZHANG Litong, CHENG Laifei, XU Yongdong, et al. Aeronaut Manuf Technol(in Chinese), 2006, 26(3): 226–232.
[7] FENG T, LI H J, SHI X B, et al. Oxidation and ablation resistance of ZrB2–SiC–Si/B-modified SiC coating for carbon/carbon composites[J]. Corros Sci, 2013, 67(97): 292–297.
[8] GOUJARD S, VANDENBULCKE L, TAWIL h. Oxidation behavior of 2D and 3D carbon/carbon thermostructural materials protected by CVD polylayer coatings[J]. Thin Solid Films, 1994, 252(2): 120–130.
[9] 张伟华, 成来飞, 刘永胜, 等. CVD–BCx在水氧环境中的自愈合机理[J]. 航空材料学报, 2014, 34(1): 27–33.
ZHANG Weihua, CHENG Laifei, LIU Yongsheng, et al. J Aeronaut Mater(in Chinese), 2014, 34(1): 27–33.  
[10] HUANG J F, DENG F, XIONG X B, et al. High performance Si-SiC composite coating for C/C composites prepared by a two-step pack cementation process[J]. Adv Eng Mater, 2010, 9(4): 322–324.
[11] ISOLA C, APPENDINO P, BOSCO F, et al. Protective glass coating for carbon-carbon composites[J]. Carbon, 1998, 36(7/8): 1213–1218.
[12] TAO X, XU XJ, XU X Q, et al. Self-healing behavior in MoSi2/borosilicate glass composite[J]. J Eur Ceram Soc, 2017, 37(2): 871–875.
[13] HUANG J F, ZHANG Y L, ZHU K J, et al. Microstructure and oxidation protection of borosilicate glass coating prepared by pulse arc discharge deposition for C/C composites[J]. Ceram Int, 2014, 41(3): 4662–4667.
[14] SMEACETTO F, FERRARIS M, SALVO M. Multilayer coating with self-sealing properties for carbon–carbon composites[J]. Carbon, 2003, 41(11): 2105–2111.
[15] LI H J, YAO X Y, ZHANG Y L, et al. Anti-oxidation properties of ZrB2 modified silicon-based multilayer coating for carbon/carbon composites at high temperatures[J]. Trans Nonfer Met Soc China, 2013, 23(7): 2094–2099.
[16] 宋永忠, 樊桢, 李兴超, 等. 碳/碳复合材料SiC/MoSi2/ZrO2涂层体系氧化烧蚀性能[J]. 复合材料学报, 2016, 33(10): 2290–2296.
SONG Yongzhong, FAN Zhen, LI Xingchao, et al. Acta Mater Compos Sin(in Chinese), 2016, 33(10): 2290–2296.
[17] FENG T, LI H J, WANG S D, et al. Boron modified multi-layer MoSi2–CrSi2–SiC–Si oxidation protective coating for carbon/carbon composites[J]. Ceram Int, 2014, 40(9): 15167–15173.
[18] SCHULTE-FISCHEDICK J, SCHMIDT J, TAMME R, et al. Oxidation behaviour of C/C–SiC coated with SiC-B4C-SiC-cordierite oxidation protection system[J]. Mater Sci Eng A, 2004, 386(1/2): 428–434.
[19] 方勋华, 易茂中, 左劲旅, 等. 航空刹车用自愈合抗氧化涂层的制备及性能[J]. 材料导报, 2006, 20(s1): 261–263. 
FANG Xunhua, YI Maozhong, ZOU Jinlv, et al. Mater Rev (in Chinese), 2006, 20(s1): 261–263.
[20] HU C L, PANG S Y, TANG S F, et al. Long-term oxidation behavior of carbon/carbon composites with a SiC/B4C–B2O3–SiO2–Al2O3 coating at low and medium temperatures[J]. Corros Sci, 2015, 94: 452–458.
[21] PARK S J, SEO M K. The effects of MoSi2 on the oxidation behavior of carbon/carbon composites[J]. Carbon, 2001, 39(8): 1229–1235.
[22] RITT P, SAKIDJA R, PEREPEZKO J H. Mo–Si–B based coating for oxidation protection of SiC–C composites[J]. Surf Coat Technol, 2012, 206(S19/S20): 4166–4172.
[23] RITT P, LU-STEFFES O, SAKIDJA R, et al. Application of plasma spraying as a precursor in the synthesis of oxidation-resistant coatings[J]. J Therm Spray Technol, 2013, 22(6): 992–1001.
[24] FENG T, LI H J, FU Q G, et al. Microstructure and anti-oxidation properties of multi-composition ceramic coatings for carbon/carbon composites[J]. Ceram Int, 2011, 37(1): 79–84.
[25] LI H J, FENG T, FU Q G, et al. Oxidation and erosion resistance of MoSi2–CrSi2–Si/SiC coated C/C composites in static and aerodynamic oxidation environment[J]. Carbon, 2010, 48(5): 1636–1642.
[26] ZHANG Y L, LI H J, QIANG Xinfa, et al. C/SiC/MoSi2–Si multilayer coatings for carbon/carbon composites for protection against oxidation[J]. Corros Sci, 2011, 53(11): 3840–3844.
[27] BARTULI C, VALENTE T, TULUI M. Plasma spray deposition and high temperature characterization of ZrB2-SiC protective coatings[J]. Surf Coat Technol, 2002, 155(2/3): 260–273.
[28] MONTEVERDE F. Ultra-high temperature HfB2–SiC ceramics consolidated by hot-pressing and spark plasma sintering[J]. J Alloy Compd, 2007, 428(1/2): 197–205.
[29] REN X R, LI H J, CHU Y H, et al. Preparation of oxidation protective ZrB2–SiC coating by in-situ reaction method on SiC–coated carbon/carbon composites[J]. Surf Coat Technol, 2014, 247(5): 61–67.
[30] REN X R, LI H J, FU Q G, et al. TaxHf1−xB2–SiC multiphase oxidation protective coating for SiC-coated carbon/carbon composites[J]. Corros Sci, 2014, 87(7): 479–488.
[31] 郭朝邦. HfB2材料研究进展[J]. 战术导弹技术, 2010(4): 32–35.
GUO Chaobang. Tactical Missile Technol(in Chinese), 2010(4): 32–35.
[32] 陈志彦, 向洁琼, 邹世钦. 3D–Cf/SiC复合材料抗高温氧化涂层结构设计与自愈合机理[J]. 功能材料, 2014, 45(17): 7116–7119.
CHEN Zhiyan, XIANG Jieqiong, ZOU Shiqin. J Funct Mater(in  
Chinese), 2014, 45(17): 7116–7119.
[33] WANG Y L, XIONG X, ZHAO X J, et al. Structural evolution and ablation mechanism of a hafnium carbide coating on a C/C composite in an oxyacetylene torch environment[J]. Corros Sci, 2012, 61(4): 156–161.
[34] 刘宝林, 刘荣军, 张长瑞, 等. SiCf/SiC复合材料高温抗氧化研究进展[J]. 硅酸盐通报, 2014, 33(5): 1107–1112.
LIU Baolin, LIU Rongjun, ZHANG Changrui, et al. Bull Chin Ceram Soc(in Chinese), 2014, 33(5): 1107–1112.
[35] ZUO Xi Z, ZHANG L T, LIU Y S, et al. Oxidation behaviour of two-dimensional C/SiC modified with self-healing Si–B–C coating in static air[J]. Corros Sci, 2012, 65: 87–93.
[36] QUEMARD L, REBILLAT F, GUETTE A. Degradation mechanisms of a SiC fiber reinforced self-sealing matrix composite in simulated combustor environments[J]. J Eur Ceram Soc, 2007, 27(1): 377–388. 
[37] 成来飞, 左新章, 刘永胜, 等. 自愈合C/SiC陶瓷基复合材料的制备工艺与性能[J]. 航空制造技术, 2014, 450(6): 24–29.
CHEN Laifei, ZUO Xinzhang, LIU Yongsheng, et al. Aeronaut Manuf Technol(in Chinese), 2014, 450(6): 24–29.
[38] FENG T, LI H J, FU Q G, et al. High-temperature erosion resistance and aerodynamic oxidation mechanism of multi-layer MoSi2–CrSi2–Si/SiC coated carbon/carbon composites in a wind tunnel at 1873 K[J]. Carbon, 2012, 50(6): 2171–2178.
[39] KIM J I, KIM W J, CHOI D J, et al. Design of a C/SiC functionally graded coating for the oxidation protection of C/C composites[J]. Carbon, 2005, 43(8): 1749–1757.
[40] CAIRO C A A, GRACA MLA, SILVA C R M, et al. Functionally gradient ceramic coating for carbon-carbon anti-oxidation protection[J]. J Eur Ceram Soc, 2001, 21(3): 325–329.
[41] LI J, LUO R Y, LIN C, et al. Oxidation resistance of a gradient self-healing coating for carbon/carbon composites[J]. Carbon, 2007, 45(13): 2471–2478.
 
 
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