硅酸盐学报

掺Al对LiNi0.85Co0.15O2结构、电化学性能和热稳定性的影响

作者：范广新刘泽萍闻寅刘宝忠

分类号：TQ152

出版年,卷(期):页码：2018,46(2):268-274

DOI：

摘要：

采用高温固相法对正极材料LiNi0.85Co0.15O2进行Al掺杂，研究了Al及其含量对材料结构、电化学性能和热稳定性的影响。结果表明：Al可进入LiNi0.85Co0.15O2晶格，占据Ni原子位置。随着掺Al量增加：材料的晶胞参数a降低、c增大、阳离子混排程度先增加后减小，晶体密度减小；电极极化逐渐增强，放电比容量依次降低，循环性能明显改善，热稳定性提高。Al掺量为5%时，LiNi0.85–xCo0.15AlxO2综合性能达到最优。掺Al不能抑制LiNi0.85–xCo0.15AlxO2在电化学循环中由H1到H2相转变，但有利于稳定材料的H2相结构，从而提高材料的综合性能。

A positive electrode material of LiNi0.85Co0.15O2 for lithium ion battery was doped with Al by a high-temperature solid state method. The effect of Al content on the structure, electrochemical properties and thermal stability of the material was investigated. The results show that Al atoms can be dissolved in LiNi0.85Co0.15O2 lattice occupying the positions of Ni atoms. The cell parameters of materials a decreases while c increases, cation mixing degree firstly increases and then decreases, the crystal density decreases gradually, the electrode polarization becomes serious, the specific discharge capacity decreases, cycle performance and thermal stability improve when Al content increases. The optimum comprehensive performance of LiNi0.85–xCo0.15AlxO2 can be obtained at Al amount of 5%. The addition of Al can not inhibit the transition of LiNi0.85–xCo0.15AlxO2 from H1 to H2 phase during electrochemical cycling, while favors to stabilize H2 phase structure of the material and improve the comprehensive properties.

基金项目：

国家自然科学基金项目(51671080, 51471065, U1304522)；河南省高校科技创新团队(16IRTSTHN005)。

作者简介：

范广新(1970—)，男，博士，副教授。

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