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铕离子掺杂碱土金属铝硼硅荧光玻璃的制备与发光性能
作者:夏李斌1 2 肖青辉1  毅1 杨雪莉1 游维雄1 
单位:(1. 江西理工大学材料科学与工程学院 江西 赣州 341000 2. 江西理工大学冶金与化学工程学院 江西 赣州 341000) 
关键词:铕离子 白光发射 碱土金属 铝硼硅酸盐玻璃 
分类号:O482.31;TQ127.2
出版年,卷(期):页码:2018,46(7):0-0
DOI:
摘要:

采用熔融冷却法在空气条件下制备了含不同碱土金属氧化物的铕离子掺杂铝硼硅酸盐玻璃Al2O3–B2O3–SiO2–Eu2O3– MO (M=Mg, Ca, Sr, Ba),考察了玻璃的密度、摩尔体积、光学碱度等物理性质,分析了玻璃的结构和发光性能。结果表明:从含Mg到含Ba玻璃,摩尔体积逐渐上升,玻璃化转变温度(Tg)依次下降。在381 nm波长激发下,所有玻璃在469 nm处均存在Eu2+的5d→4f跃迁发射,在615 nm处存在Eu3+的5D0→7F2跃迁发射,表明玻璃在空气中实现了Eu3+→Eu2+的部分还原,其中在含Sr玻璃中,Eu3+还原程度相对最大,Eu2+发光最强。所有玻璃均为非晶态,结构中存在的[BO4]、[AlO4]、[SiO4]四面体网络结构,有利于屏蔽Eu2+不被氧化。从含Mg到含Ba玻璃,四面体网络Q4结构单元中桥氧键断裂程度上升,形成更多的Q3、Q2结构单元,使玻璃结构对称性、致密性下降。在近紫外光激发下,玻璃发光色坐标均位于白光区域内,表明该系列铕离子掺杂铝硼硅玻璃在白光LED上存在潜在应用。

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参考文献:
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