首页期刊信息编委及顾问期刊发行联系方式使用帮助常见问题ENGLISH
位置:首页 >> 正文
利用悬浮熔炼法制备含氮铝酸盐玻璃
作者:徐诚1 刘小峰1 邱建荣2 
单位:1. 浙江大学材料科学与工程学院 杭州 310027 2. 浙江大学光电科学与工程学院 杭州 310027 
关键词:悬浮熔炼 含氮玻璃 硬度 析晶 
分类号:TU528
出版年,卷(期):页码:2018,46(11):0-0
DOI:10.14062/j.issn.0454-5648.2018.11.0
摘要:

 利用悬浮熔炼技术制备了组成为46Ta2O5–(54–x)Al2O3–2xAlN的含氮铝酸盐玻璃,并对玻璃的结构以及热力学特性、光学性能和力学性能进行表征。氮含量的增加,导致玻璃光学通过率降低,折射率、密度、硬度和杨氏模量分别增加了3.8%、2.0%、4.8%和3.9%。利用XPS技术直接证明了氮元素进入了玻璃网络结构。氮元素取代部分氧进入玻璃结构形成Al–N键,由于N原子的三配位特性和玻璃结构变得更加紧密,导致玻璃的折射率、密度、硬度、弹性模量增加,但玻璃的析晶倾向增强。

 Tantalum aluminate glasses containing nitrogen with the composition of 46Ta2O5–(54–x)Al2O3–2xAlN (mole fraction, %) were prepared by a containerless process. The structural and thermodynamic characteristics as well as the optical and mechanical properties were investigated. The increase of nitrogen content led to reduction of glass optical transmittance, and the refractive index, density, hardness and Young’s modulus increased by 3.8%、2.0%、4.8% and 3.9%, respectively. XPS showed that the direct evidence of the existence of N in glass structure. Introduction of N into the glass structure by replacing O results in the formation of Al—N bond. The cross-link of glass structures becomes tighter due to the three-coordinated characteristic of N, thus increasing the refractive index, density, hardness and elastic modulus of glass. However, the crystallization tendency of glass increases.

基金项目:
国家自然科学基金(51472091、11504323、1775192和51772270);中国科学院上海光学精密机械研究所强场激光物理国家重点实验室开放课题基金。
作者简介:
参考文献:
[1] SAKKA S. Oxynitride glasses[J]. Ann Rev Mater Res, 1986, 16(16): 29–46.
[2] MESSIER D R, BROZ A. Microhardness and elastic moduli of Si-Y-A1-O-N glasses[J]. J Am Ceram Soc, 2010, 65(8): c123–c123.
[3] LOEHMAN R E. Preparation and properties of oxynitride glasses[J]. J Non-Cryst Solids, 1983, 56(1/3): 123–134.
[4] LOEHMAN R E. Oxynitride glasses[J]. J Non-Cryst Solids, 1980, 42(1/3): 433–445.
[5] HAMPSHIRE S. Oxynitride glasses and their properties-an overview[J]. Key Eng Mater, 2003, 247: 155–160.
[6] DREW R A L, HAMPSHIRE S, JACK K H. The Preparation and Properties of Oxynitride Glasses[M]. Netherlands, Springer, 1983.
[7] COON D N, RAPP J G, BRADT R C, et al. Mechanical properties of silicon-oxynitride glasses[J]. J Non-Cryst Solids, 1983, 56(1/3): 161–165.
[8] ZHANG E, LIDDELL K, THOMPSON D P. Glass forming regions and thermal expansion of some Ln-Si-Al-O-N glasses (Ln=La, Nd)[J]. Brit Ceram T, 1996, 95(4): 169–172.
[9] YAO L, FANG Q, HU G, et al. Preparation and properties of some Li-Al-Si-O-N glasses[J]. J Non-Cryst Solids, 1983, 56(1): 167–172.
[10] TREDWAY W K, RISBUD S H. Melt processing and properties of barium-sialon glasses[J]. J Am Ceram Soc, 2010, 66(5): 324–327.
[11] SAKKA S, KAMIYA K, YOKO T. Preparation and properties of Ca-Al-Si-O-N oxynitride glasses[J]. J Non-Cryst Solids, 1983, 56(1): 147–152.
[12] REDINGTON W, REDINGTON M, HAMPSHIRE S, et al. Properties of some high Al content glasses in various lanthanide-Si-Al-O-N systems[J]. J Non-Cryst Solids, 2003, 316(1): 74–81.
[13] OHASHI M, NAKAMURA K, HIRAO K, et al. Formation and properties of Ln-Si-O-N glasses (Ln=lanthanides or Y)[J]. J Am Ceram Soc, 1995, 78(1): 71–76.
[14] MURAKAMI Y, YAMAMOTO H. Properties of oxynitride glasses in the Ln-Si-Al-O-N systems (Ln=rare-earth)[J]. Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi, 1994, 102(1183): 231–236.
[15] MAKISHIMA A, MITOMO M, II N, et al. Microhardness and transparency of an La-Si-O-N oxynitride glass[J]. J Am Ceram Soc, 2010, 66(3): C55–C56.
[16] LOEHMAN R E. Preparation and properties of yttrium-silicon- aluminum oxynitride Glasses[J]. J Am Ceram Soc, 1979, 62(9/10): 491–494.
[17] JACK K H. Nitrogen ceramics[J]. Endeavour, 1987, 11(2): 80–87.
[18] HOMENY J, MCGARRY D L. Preparation and mechanical properties of Mg-Al-Si-O-N glasses[J]. J Am Ceram Soc, 2010, 67(11): c225–c227.
[19] SHARAFAT A, GRINS J, ESMAEILZADEH S. Glass-forming region in the Ca–Si–O–N system using CaH as Ca source[J]. J Eur Ceram Soc, 2008, 28(14): 2659–2664.
[20] SHARAFAT A, FORSLUND B, GRINS J, et al. Formation and properties of nitrogen-rich strontium silicon oxynitride glasses[J]. J Mater Sci, 2009, 44(2): 664–670.
[21] HAKEEM A S, GRINS J, ESMAEILZADEH S. La–Si–O–N glasses : Part I. Extension of the glass forming region[J]. J Eur Ceram Soc, 2007, 27(16): 4773–4781.
[22] HAKEEM A S, DAUCÉ R, LEONOVA E, et al. Silicate glasses with unprecedented high nitrogen and electropositive metal contents obtained by using metals as precursors[J]. Adv Mater, 2005, 17(18): 2214–2216.
[23] ALI S, BO J. Glasses in the Ba-Si-O-N system[J]. J Am Ceram Soc, 2011, 94(9): 2912–2917.
[24] GRESKOVICH C, PROCHAZKA S. Stability of Si3N4 and liquid phase(s) during sintering[J]. J Am Ceram Soc, 2010, 64(7): C-96-C-97.
[25] FRISCHAT G H, SCHRMPF C. Preparation of nitrogen-containing Na2O-CaO-SiO2 glasses[J]. J Am Ceram Soc, 1980, 63(11/12): 714–715.
[26] MESSIER D R, DEGUIRE E J. Thermal decomposition in the system Si-Y-AI-O-N[J]. J Am Ceram Soc, 2010, 67(9): 602–605.
[27] ROSALESSOSA G A, MASUNO A, HIGO Y, et al. High elastic moduli of a 54Al2O3-46Ta2O5 glass fabricated via containerless processing[J]. Sci Rep, 2015, 5: 15233.
[28] VIDEAU J J, ETOURNEAU J, ROCHERULLE J, et al. Structural approach of sialon glasses: M-Si-Al-O-N[J]. J Eur Ceram Soc, 1997, 17(15–16): 1955–1961.
[29] SUN E Y, BECHER P F, HWANG S L, et al. Properties of silicon aluminum yttrium oxynitride glasses[J]. J Non-Cryst Solids, 1996, 208(1): 162–169.
[30] HAKEEM A S. Novel route of oxynitride glass synthesis and characterisation of glasses in the Ln-Si-O-N and Ln-Si-Al-O-N systems[R]. Research Gate,2007.
[31] ESMAEILZADEH S, GRINS J, SHARAFAT A. Glass forming region in Ca-Si-O-N system using CaH2 as Ca source[J]. J Eur Ceram Soc, 2008, 28(14): 2659–2664.
[32] ALI S, BO J. Compositional effects on the properties of high nitrogen content alkaline-earth silicon oxynitride glasses, AE=Mg, Ca, Sr, Ba[J]. J Eur Ceram Soc, 2011, 31(4): 611–618.
[33] COON D N, DOYLE T E, WEIDNER J R. Refractive indices of glasses in the Y-Al-Si-O-N system[J]. J Non-Cryst Solids, 1989, 108(2): 180–186.
[34] RAND M J, STANDLEY R D. Silicon oxynitride films on fused silica for optical waveguides[J]. Appl Opt, 1972, 11(11): 2482–2488.
[35] MAKEHIMA A, TAMURA Y, SAKAINO T. Elastic moduli and refractive indices of aluminosilicate glasses containing Y2O3, La2O3, and TiO2[J]. J Am Ceram Soc, 1978, 61(5–6): 247–249.
[36] BROW R, PANTANO C, BOYD D C. Nitrogen coordination in oxynitride glasses[J]. J Am Ceram Soc, 1984, 67(4): c72–c74.
[37] SHARAFAT A, GRINS J, ESMAEILZADEH S. Hardness and refractive index of Ca–Si–O–N glasses[J]. J Non-Cryst Solids, 2009, 355(4–5): 301–304.
[38] HANADA T, UEDA N, SOGA N. Preparation, properties and bond character of nitrogen in calcium silicon oxynitride glasses[J]. J Ceram Soc Jpn, 2010, 96(1111): 284–291.
[39] SCHNEIDER M, GASPAROV V A, RICHTER W, et al. XPS studies on oxynitride glasses in the system Si-Al-O-N[J]. J Non-Cryst Solids, 1997, 215(2–3): 201–207.
[40] WILKS J A, MAGTOTO N P, KELBER J A, et al. Interfacial reactions during sputter deposition of Ta and TaN films on organosilicate glass: XPS and TEM results[J]. Appl Surf Sci, 2007, 253(14): 6176–6184.
[41] DELSARTE S, SERIN V, FLANK A M, et al. Structural investigation of mixed nitrided galloaluminophosphates “AlGaPON” by EELS, XAS, and XPS spectroscopies[J]. J Solid State Chem, 2002, 163(1): 163–177.
[42] WETHERALL K M, DOUGHTY P, MOUNTJOY G, et al. The atomic structure of niobium and tantalum containing borophosphate glasses[J]. J Phys Condens Matter , 2009, 21(37): 375106.
[43] RUSSO U, LOVISETTO B, MARSON S, et al. Mössbauer and optical spectroscopy of phosphoniobate and phosphotantalate glasses doped with iron[J]. Philosl Mag Part B, 2001, 81(3): 313–320.
[44] MCMILLAN P, PIRIOU B. Raman-spectroscopy of aman-spectroscopy of calcium aluminate glass and crystals[J]. J Non-Cryst Solids, 1983, 55(2): 221–242.
[45] NEUVILLE D R, HEMDERSON G S, CORMIER L, et al. The structure of crystals, glasses, and melts along the CaO-Al2O3 join: Results from Raman, Al L- and K-edge X-ray absorption, and Al-27 NMR spectroscopy[J]. Am Miner, 2010, 95(10): 1580–1589.
[46] LICHERON M, MONTOUILLOUT V, MILLOT F, et al. Raman and Al-27 NMR structure investigations of aluminate glasses: (1-x)Al2O3-x MO, with M=Ca, Sr, Ba and 0.5<x<0.75)[J]. J Non-Cryst Solids, 2011, 357(15): 2796–2801.
[47] MEI Q, BENMORE C J, SAMPATH S, et al. The structure of permanently densified CaAl2O4 glass[J]. J Phys Chem Solids, 2007, 68(2): 315–315.
 
服务与反馈:
文章下载】【加入收藏
中国硅酸盐学会《硅酸盐学报》编辑室
京ICP备10016537号-2
京公网安备 11010802024188号
地址:北京市海淀区三里河路11号    邮政编码:100831
电话:010-57811253  57811254    
E-mail:jccs@ceramsoc.com