硅酸盐学报

陶瓷抛光渣对水泥基材料碱集料反应的影响

作者：魏丽丽1 2 胡明玉1 郑江1 陈露璐1 付超1

单位：1. 南昌大学建筑工程学院南昌330031 2. 赤峰学院建筑与机械工程学院内蒙古赤峰024000

关键词：陶瓷抛光渣矿渣碱集料反应抑制机理强度

分类号：TQ172

出版年,卷(期):页码：2018,46(11):0-0

DOI：10.14062/j.issn.0454-5648.2018.11.11

摘要：

以0%、20%、30%、40%陶瓷抛光渣等量取代水泥制备砂浆试样，矿渣作对比试验，通过膨胀率、强度测定、扫描电子显微镜观察和能谱分析，研究陶瓷抛光渣对水泥基材料碱集料反应的影响规律，揭示矿物掺合料抑制碱集料反应的机理。结果表明：陶瓷抛光渣能有效抑制水泥基材料的碱集料反应膨胀，且其抑制作用比矿渣更显著；两种掺合料使集料与胶凝材料界面区结构更密实，界面宽度更小；抛光渣的合理掺量为20%~30%、矿渣掺量应>30%。矿物掺合料抑制碱集料反应的机理为界面过渡区中Ca/Si比降低使集料表面碱度降低，降低了近集料区域生成高Na/Si比膨胀性产物的可能性，并且K+和Al3+在近集料处富集，形成非膨胀性产物。由于体系中Al2O3的存在，使K+对碱集料反应的作用低于Na+的作用。

The influence of ceramic polishing powder on the alkali-aggregate reaction of cement-based materials was investigated. The mortar specimens were prepared by replacing 0%, 20%, 30%, and 40% of cement with the same amount of ceramic polishing powder. The expansion rate and strength were measured. The inhibition mechanism of the mineral admixture on the alkali-aggregate reaction was analyzed by scanning electron microscopy and energy disperse spectroscopy. The results show that ceramic polishing powder can restrain alkali-aggregate reaction of cement based materials. The inhibition effect on alkali-aggregate reaction of ceramic polishing powder is greater than that of slag. The mortar specimens modified with the two mixtures have a larger density and a smaller porosity, and the width of interfacial transition zone is narrower. The optimum content of the ceramic polishing powder is 20%–30% and the content of slag is greater than 30% to inhibit the expansion of alkali-aggregate reaction effectively and achieve the requirements of strength as well. Also, the reduction of Ca/Si ratio in the interfacial transition zone can reduce the alkalinity on the surface of aggregate. The possibility of producing expansibility products with a high Na/Si ratio in the aggregate region decreases. The accumulation of K+ and Al3+ions in the aggregates can generate the non-expansive product, which is the mechanism of the mineral admixture inhibition in the alkali-aggregate reaction. In addition, the effect of K+ions on the alkali-aggregate reaction is weaker than that of Na+ions due to the existence of Al2O3 in the system.

基金项目：

国家自然科学基金(51068023)资助。

作者简介：

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