硅酸盐学报

Zn1–xCax(Ti0.6Zr0.4)Nb2O8陶瓷的微波介电性能

作者：谢志翔1 3 黄雨佳1 李月明1 2 3 沈宗洋1 2 宋福生1 李志科1

单位：(1. 景德镇陶瓷大学材料科学与工程学院江西景德镇 333403 2. 中国轻工业功能陶瓷材料重点实验室江西景德镇 333403 3. 江西省能量存储与转换陶瓷材料工程实验室江西景德镇 333403)

分类号：TQ174

出版年,卷(期):页码：2019,47(3):0-0

DOI：

摘要：

采用传统固相反应法制备Zn1–xCaxTi0.6Zr0.4Nb2O8 (x=0.05, 0.10, 0.20, 0.30)微波介质陶瓷，研究了不同Ca2+取代量对Zn1–xCaxTi0.6Zr0.4Nb2O8陶瓷的物相组成、显微结构及微波介电性能的影响，利用X射线衍射仪、扫描电子显微镜和网络分析仪等对其晶体结构、微观形貌及微波介电性能进行表征。结果表明：Ca2+取代Zn2+会导致CaNb2O6第二相的形成，且随Ca2+含量的增加，ZnTiNb2O8相含量减少；CaNb2O6相的含量增加，导致Zn1–xCaxTi0.6Zr0.4Nb2O8陶瓷的介电常数和品质因数减小，谐振频率温度系数向正方向移动。当x=0.3时，Zn1-xCaxTi0.6Zr0.4Nb2O8陶瓷在1 140 ℃烧结并获得最佳微波介电性能：εr=30.42，Q?f=47 280 GHz，τf=–25.37×10–6/℃。

Zn1–xCaxTi0.6Zr0.4Nb2O8(x = 0.05, 0.10, 0.20, 0.30) microwave dielectric ceramics were prepared by a solid-state reaction method. The effect of Ca2+ substitution amount on the phase composition, microstructure and microwave dielectric properties of Zn1–xCaxTi0.6Zr0.4Nb2O8 ceramics was investigated by X-ray diffraction, scanning electron microscopy and network analysis, respectively. The results show that Ca2+ substitution of Zn2+ leads to the formation of the second phase of CaNb2O6, the content of ZnTiNb2O8 phase decreases and the content of CaNb2O6 phase increases with the increase of Ca2+ content, leading to the decrease of dielectric constant εr and quality factor Q?f of Zn1–xCaxTi0.6Zr0.4Nb2O8 ceramics, and the temperature coefficient of resonant frequency τf shifting to a positive direction. The optimum microwave dielectric properties (i.e., εr=30.42, Q?f=47 280 GHz, τf= –25.37×10–6/℃) are obtained when Zn1–xCaxTi0.6Zr0.4Nb2O8 ceramic is sintered at 1 140 ℃ as x=0.3.

基金项目：

江西省“赣鄱英才555工程”领军人才计划；国家自然科学基金(51402136)；江西省自然科学基金(20171BAB216008)资助。

作者简介：

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