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基于对称双阴极结构固体氧化物燃料电池乙醇燃料内直接重整的电化学性能
作者:汝艳雷1 2 王建新2 李卓斌3 邬荣敏3 夏长荣1 官万兵2 
单位:(1. 中国科学技术大学纳米科学技术学院 江苏 苏州 215123 2. 中国科学院宁波材料技术与工程研究所  浙江 宁波 315201 3. 浙江浙能技术研究院有限公司 杭州 311121) 
关键词:乙醇燃料 内重整 对称双阴极 固体氧化物燃料电池 
分类号:TM911
出版年,卷(期):页码:2020,48(3):0-0
DOI:
摘要:

 对乙醇燃料应用到新型对称双阴极结构固体氧化物燃料电池中直接内重整反应运行进行了探索研究。结果显示,将乙醇以一定的水醇比通入到电池中在输出功率密度为0.137 W/cm2@0.8 V下运行超过100 h依然保持稳定,电池内部发生轻微的积碳现象,表明该新型结构电池可进行碳基燃料直接内重整运行,具有较好的应用前景。

 The performance of direct internal reforming of ethanol as a fuel in a flat tube solid oxide fuel cell based on double-sided cathodes was investigated. The results show that the cell can operate stably for 100 hours with a power density of 0.137 W/cm2@0.8 V when ethanol is injected into the cell at a constant water to carbon ratio. A slight carbon deposition only occurs inside the cell. The structure cell can be applied for direct internal reforming of carbon-containing fuels, indicating a promising potential for use.

基金项目:
国家重点研发计划(2018YFB1502600);国家自然科学基金(51702333);浙江省能源集团有限公司科技项目(ZNKJ-2018- 008)
作者简介:
参考文献:

 [1]YANG B C, KOO J, SHIN J W, et al. Direct alcohol–fueled low–temperature solid oxide fuel cells: a review[J]. Energy Technology, 2019, 7(1): 5–19.

[2]WANG W, QU J, JULIAO P S B, et al. Recent advances in the development of anode materials for solid oxide fuel cells utilizing liquid oxygenated hydrocarbon fuels: a mini review[J]. Energy Technology, 2019, 7(1): 33–44.
[3]CHEN B, XU H, TAN P, et al. Thermal modeling of ethanol-fuelled solid oxide fuel cells[J]. Appl Energ, 2019, 237: 476–486.
[4]GE Xiao–Ming, CHAN Siew–Hwa, LIU Qing–Lin, et al. Solid oxide fuel cell anode materials for direct hydrocarbon utilization[J]. Adv Energ Mater, 2012, 2(10): 1156–1181.
[5]SUMI H, YAMAGUCHI T, SHIMADA H, et al. Internal partial oxidation reforming of butane and steam reforming of ethanol for anode-supported micro tubular solid oxide fuel cells[J]. Fuel Cells, 2017, 17(6): 875–881.
[6]POMFRET M B, STEINHURST D A, OWRUTSKY J C. Ni/YSZ solid oxide fuel cell anodes operating on humidified ethanol fuel feeds: An optical study[J]. J Power Sources, 2013, 233: 331–340.
[7]GIRONA K, SAILLER S, GELIN P, et al. Modeling of gradual internal reforming process over Ni–YSZ SOFC anode with a catalytic layer[J]. Can J Chem Eng, 2015, 93(2): 285–296.
[8]高国栋. 乙醇为燃料的固体氧化物燃料电池性能研究[D]. 大连: 大连理工大学, 2008.
GAO Guodong. Research on performance of SOFC using ethanol as fuel. (in Chinese, dissertation). Dalian: Dalian University of Technology, 2008.
[9]CORRE G P, IRVINE J T. Studies on direct ethanol use in SOFCs[J]. ECS Transactions, 2011, 35(1): 2845–2854
[10]NOBREGA S D, GALESCOM V, GIRONA K, et al. Direct ethanol solid oxide fuel cell operating in gradual internal reforming[J]. J Power Sources, 2012, 213: 156–159.
[11]LIANGLIANG S, ZHIMIN H, LINGHONG L, et al. Application of Ru nano flowers doped Ni–YSZ anode in ethanol-fueled SOFC[J]. Rare Metal Mat Eng, 2017, 46(8): 2322–2326.
[12]NOBREGA S D, FONSECA F C, GELIN P, et al. Gradual internal reforming of ethanol in solid oxide fuel cells[J]. Energy Procedia, 2012, 28: 28–36.
[13]FARREL B, LINIC S. Direct electrochemical oxidation of ethanol on SOFCs: Improved carbon tolerance of Ni anode by alloying[J]. Appl. Catal. B– Environ, 2016, 183: 386–393.
[14]高珠, 刘鹏翔, 苏海兰, 等. 固体氧化物燃料电池阳极材料的抗积炭方法[J]. 工业催化, 2018, 26(10): 43–47.
GAO Zhu, LIU Pengxiang, SU Hailan, et al. Ind Catal (in Chinese), 2018, 26(10): 43–47.
[15]AZIMOVA M A, MCINTOSH S. On the choice of anode electrocatalyst for alcohol fuelled proton conducting solid oxide fuel cells[J]. J Electrochem Soc, 2011, 158(12): B1532–B1538.
[16]LIANG C, LING–HONG L, JI–JUN S, et al. Ni/YSZ anode impregnated La2O3 on anti–carbon deposition of SOFC cell[J]. J Inorg Mater, 2017, 32(3): 241–246.
[17]LIU W, ZOU Z, MIAO F, et al. Anode–supported planar solid oxide fuel cells based on double-sided cathodes[J]. Energy Technol, 2019, 7(2): 240–244.
[18]LI X, WANG Y, LIU W, et al. Reliability of CO2 electrolysis by solid oxide electrolysis cells with a flat tube based on a composite double-sided air electrode[J]. Compos Part B–Eng, 2019, 166: 549–554.
[19]邹志文, 刘武, 蒋龙, 等. 中空对称双阴极结构电池的高温抗氧化还原特性[J]. 硅酸盐学报, 2019, 47: 308–312.
ZOU Zhiwen, LIU Wu, JIANG Long, et al. J Chin Ceram Soc, 2019, 47: 308–312.
[20]卜瑶, 官万兵, 刘武. 稀薄燃料气氛下中空全对称双阴极SOFC的电化学特性[J]. 硅酸盐学报, 2018, 6: 873–878.
BU Yao, GUAN Wanbing, LIU Wu, J Chin Ceram Soc, 2018, 6: 873–878.
[21]LEONE P, LANZINI A, ORTIGOZA–VILLALBA G A, et al. Operation of a solid oxide fuel cell under direct internal reforming of liquid fuels[J]. Chem Eng J, 2012, 191: 349–355.
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